Title : Effect of micaceous iron oxide (MIO) and nano crystalline Al on the electrochemical behavior of aliphatic amine cured epoxy coating
Abstract:
Three coating formulations were fabricated by incorporating different percentages of MIO (1, 2 and wt%) with ball milled nano crystalline Al (2 wt%) particles which was optimized earlier. These coatings were characterized by means of different methods; namely, SEM, TGA, pendulum hardness, scratch test, and nano-indentation. The EIS measurements were carried out to report the effect of adding MIO powder in fabricated coatings on their corrosion behavior in 3.5 wt% NaCl solutions. In order to report the effect of immersion time on the corrosion and degradation of the prepared coatings, the EIS data were also acquired after various exposure periods of time, i.e. 1 h, 7 d, 14 d, 21 d, and 30 d in the test chloride solution. It has been found that the obtained EIS data for the fabricated coatings proved that the presence of 2% MIO provided the highest corrosion resistance amongst all coatings and that effect was recorded after all immersion periods of time. But the MIO incorporated coatings has less corrosion resistance than Al based epoxy coatings. It was also shown that with prolonged immersion the resistance to corrosion declined after 7d then with longer period of immersion i.e 14 d, 21 d, and 30 d increases the resistance to corrosion by forming oxide products on the coatings surface. The results obtained from both mechanical and electrochemical testing confirmed that the fabricated coating with 2 wt% Al exhibited better hardness and higher resistance to corrosion as compared t to coatings with 1 wt% Al and 3 wt% Al.
Audience Take-Away:
- The audience can understand the corrosion resistance can be enhanced with the nanocrystalline materials
- The coating companies can use the nano pigments to protect structures.
- The faculties can understand the processing of nano pigmented coatings and mechanism of corrosion resistance.
- It Does provide a practical solution to a problem that could simplify or make a designer’s job more efficient
- It will improve the accuracy of a design, or provide new information to assist in a design problem
- Mechanical and electrochemical corrosion resistance properties increase
